Product ID:GENESOLV 2010 SOLVENT
MSDS Date:08/01/1989
FSC:6850
NIIN:00N026114
MSDS Number: BRJPX

ALLIED-SIGNAL INC

MORRISTOWN, NJ 07962
US

Emergency Phone: 201-455-2000; 312-450-3900

Info Phone: 201-455-2000; 312-450-3900

Cage: 1L164

ALLIED-SIGNAL INC

2332R MORRISTOWN, NJ 07962-2332 US

Telephone: 201-455-4414

Cage: 1L164

CLEAN WATER ACT, RCRA, AS WELL AS OTHER RELEVANT

RTECS: 9999999ZZ

IN OPER, UNLBLD,MISLABELED CNTNRS.STORE IN

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SURFS/ELEC ARCS CAN DECOMP TO FORM HYDROGEN

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HNDLG/STOR & USE PROCS

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SPILL/LEAK HAS POTNTL TO CAUSE UNDERGROUND WATER

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SOURCE UNFIT FOR HUMAN CONSUMPTION. CONTAMINATION

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MONITORING OF WORKPLACE TO ENSURE EXPOS LIMITS

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DERM/OTHER HLTH EFTS.DO NOT TAKE INTERNALLY.

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NEVER ALONE, ALWAYS

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PROT WHEN EXPOS TO VAPS IS POSS. NO SMOKING IN AREA

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OPEN FLAMES/HOT SURFS. HEAT AND/OR UV RADIATION MAY

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OR POORLY VENT SPACE CAN BE IGNITED W/FLAME/HIGH

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FLUORIDES, CHLORIDES, AND PHOSGENE .

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ETHANE, 1,1-DICHLORO-1-FLUORO-; (DICHLOROFLUOROETHANE)

CAS: 1717-00-6

RTECS: KI0997000

Fraction By Weight: 86.1%

ETHANE,2,2-DICHLORO-1,1,1-TRIFLUORO-;

CAS: 306-83-2

RTECS: KI1108000

Fraction By Weight: 10% (WT)

METHANOL

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 3.6%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHANE, NITRO-; (NITROMETHANE)

CAS: 75-52-5

RTECS: PA9800000

Fraction By Weight: 0.3%

OSHA PEL 100 PPM

ACGIH TLV: 20 PPM

FLUSH W/LRG AMTS OF

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WASH

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CONTAMD CLOTHING AND SHOES. GET MEDICAL ATTN IMMED.

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RECOVER/ABSORB SPILLED MATL ON

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TRACES HAVE BEEN REMOVED, THORO WET VACUUM AREA.DO

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AS MUCH CONTAMINATED EARTH AND GRAVEL, ETC. AS

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&/THEIR CNTNRS TO PVNT ENVIRON CONTAM.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:AT LOW LEVEL OF CONC INITIAL
SYMPS MAY INCL HDCH, DIZZ, NAUS, LOSS OF CONC,& IRRIT. W/HIGH EXPOS
LEVS: INTOX, CARDIAC ARRHYTHMIA. PROD VAPS DISPLACE AIR & CAN CAUSE
ASPHYXIATION ESPEC IN CONFINE D SPACES. INGEST: SIMILAR SYMPTS AS
FORINHAL. DISCOMFORT DUE TO VOLAT WOULD BE EXPECTED. IN SUFF QTYS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CAN CAUSE EYE DMG INCL BLINDNESS DUE
TO METHANOL COMPONENT. SKIN: DEFAT OF SKIN CAN CAUSE IRRIT. NO
ABSORP TOX DATA IS AVAIL. EYES: IRRIT: LIQ CONT WILL IRRIT EYES &
MAY CAUSE CONJUNCTIVITIS . IN 90 DAY STUDY(RATS) AT 1,000 PPM; WT
LOSS WAS OBSERVED & AT HIGHER LEVELS, MILD LIVER DMG HAS BEEN
REPORTED (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE TO FRESH AIR. GIVE ARTF RESP IF BRTHG HAS
STOPPED. GIVE O*2 AS NEC IF QUALIFIED OP IS AVAIL. DO NOT GIVE
ADRENALIN (EPINEPHRINE). GET MD ATTN IMMED. INGEST: IF CONSCIOUS,
INDUCE VOM IMME D BY GIVING 2-4 GLASSES OF WATER & TOUCHING FINGER
TO BACK OF THROAT/REMOVE CHEM BY GASTRIC LAVAGE. DO NOT GIVE
STIMULANTS. GET MED ATTN IMMED. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCON PERS (ING 5)

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:8.0%
Upper Limits:19%
Extinguishing Media:CO*2, DRY CHEMICAL OR WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESS DEMAND SCBA &
FULL PROT EQUIP. POSS EXPOS TO HYDROCHLORIC & HYDROFLUORIC ACIDS &
PHOSGENE. USE H*2O SPRAY TO COOL CNTNRS.
Unusual Fire/Explosion Hazard:WILL DECOMP AT TEMPS >250C. DECOMP PROD
INCLUDE HYDROCHLORIC & HYDROFLUORIC ACIDS & CARBONYL HALIDES SUCH
AS PHOSGENE. VAPS CONCENTRATED IN CONFINED(ING 23)

Spill Release Procedures:IMMED EVAC AREA & PROVIDE MAX VENT. UNPROT
PERS SHLD MOVE UPWIND OF SPILL. ONLY PERS EQUIPPED W/PROPER RESP &
SKIN/EYE PROT SHLD BE PERMITTED IN AREA. DIKE AREA TO CONTAIN
SPILL. TAKE PRECS AS NEC TO PVNT CONTAM OF GROUND & SURF WATERS
(ING 8)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT USE IN POORLY VENT/CONFINED
SPACES. PROD VAPS ARE HVR/AIR & WILL COLLECT IN LOW AREAS. KEEP
CNTNR CLSD WHEN NOT IN USE. DO NOT STORE (ING 13)
Other Precautions:AVOID PRLNGD/RPTD BRTHG OF VAPS. HIGH VAP CONCS CAN
CAUSE DIZZ, UNCON/DEATH. USE ONLY W/ADEQ VENT. VENT MUST BE SUFF TO
LMT EMPLOYEE EXPOS TO PROD BELOW OSHA PERMISSIBLE EXPOS LMTS(8 HR
TWA). ALLIED-S IGNAL RECOMM ROUTINE AIR (ING 18)

Respiratory Protection:NONE REQUIRED FOR ADEQUATELY VENTED WORK
SITUATIONS. USE NIOSH/MSHA APPROVED SCBA/SUPPLIED-AIR RESP FOR
EMERGENCIES & IN SITUATIONS WHERE AIR MAY BE DISPLACED BY VAPORS.
Ventilation:LOC EXHST: AT FILLING ZONES & WHERE LEAKAGE IS PROB.
MECH:(GENL): ADEQUATE FOR STORAGE AREAS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:SAFETY SHOWER & EYE-WASH FOUNTAIN IN IMMED
AREA. PERS PROT CLTHG & USE OF EQUIP MUST BE IN ACCORDANCE W/29 CFR
1910.132.
Work Hygienic Practices:CONTACT LENSES SHLD NOT BE WORN UNDER SUCH
CNDTNS. DO NOT EAT, DRINK OR SMOKE IN WORK AREAS.
Supplemental Safety and Health
EFTS OF OVEREXP: IN RATS & DOGS. CHLOROFLUOROCARBON MATLS HAVE PRDCED
SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE
SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE C
ONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR
CHRONICALLY EXPOS TO CHLOROFLUOROCARBONS .

HCC:T6
Boiling Pt:B.P. Text:85.2F,29.6C
Decomp Temp:Decomp Text:>250C,482F
Vapor Pres:11.3 PSIA
Vapor Density:4.05 AIR/1
Spec Gravity:1.21 @ 70F
pH:NEUTRL
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:BELIEVED SLIGHT
Appearance and Odor:COLORLESS LIQUID WITH ETHEREAL AND FAINT SWEETISH
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALKALIS, REACTIVE METALS, (PWDRD AL, NA, K, CA, MG, ZN,
MOLTEN AL, BA & LI SHAVINGS. STRONG OXIDIZERS.
Stability Condition to Avoid:AVOID SPARKS, HOT SPOTS, WELDING, FLAMES
AND CIGARETTES.
Hazardous Decomposition Products:HYDROCHLORIC & HYDROFLUORIC ACIDS, AND
CARBONYL HALIDES SUCH AS PHOSGENE. CHLORIDES, FLUORIDES .

Waste Disposal Methods:CONTAMD SAWDUST, VERMICULITE/POROUS SURF MUST BE
DISP OF IN PERMITTED HAZ WASTE MGMT FACILITY. RECOVERED LIQS MAY BE
REPROCESSED/INCIN/MUST BE TREATED IN PERMITTED HAZ WASTE MGMT
FACILITY. CARE MUST B E TAKEN WHEN USING/DISP OF CHEM MATLS (ING
11)

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particular situation.